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sodium persulfate : ウィキペディア英語版
sodium persulfate

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Sodium persulfate is the inorganic compound with the formula Na2S2O8. It is the sodium salt of persulfate (also called peroxydisulfate), an oxidizer. It is a white solid that dissolves in water. It is almost non-hygroscopic and has good shelf-life.
==Production==
The salt is prepared by the electrolytic oxidation of sodium hydrogen sulfate:
:2 NaHSO4 → Na2S2O8 + H2
Oxidation is conducted at a platinum anode.〔Pietzsch, A.; Adolph, G. J. Chem. Technol. Biotechnol. 1911, 30, 85.〕 In this way about 165,000 tons were produced in 2005.
The standard redox potential of sodium persulfate into hydrogen sulfate is 2.1 V, which is higher than that of hydrogen peroxide (1.8 V) but lower than ozone (2.2 V).〔Block, Philip A., Richard A. Brown, and David Robinson. "Novel activation technologies for sodium persulfate in situ chemical oxidation." Proceedings of the Fourth International Conference on the remediation of chlorinated and recalcitrant compounds. 2004.〕 The sulfate radical formed in situ has a standard electrode potential of 2.7 V.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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